Comparative studies on Cr(VI) ions by reduced graphene oxide and SBA-16 mesoporous silica and their composites with Cu-MOF

Fathy, Nady A; Abas, Khadiga; Mohamed, Ghada; Sayed Ahmed, Sohair A.; Abdelmoaty, Alaa Salah

doi:10.21608/ejchem.2025.365156.11383

Comparative studies on Cr(VI) ions by reduced graphene oxide and SBA-16 mesoporous silica and their composites with Cu-MOF

Articles in Press

Document Type : Original Article

Authors

¹ Physical Chemistry, Inorganic chemical industries division, National Research Centre,

² Researcher, Nrc

³ Physical chemistry department, inorganic chemical industries, national research centre

⁴ Physical Chemistry Department, NRC

⁵ inorganic chemistry, faculty of science, national research centre.

10.21608/ejchem.2025.365156.11383

Abstract

This work examines the adsorption performance of novel adsorbents such as reduced graphene oxide (GO) and mesoporous silica (SBA-16) which synthesized from rice husk ash, and then composited with Cu-metal organic framework (Cu-MOF) for the first time. XRD, FTIR, EDX, FE-SEM and N2 adsorption techniques were studied. The adsorption performance of investigated adsorbents toward removal of hexavalent chromium (Cr(VI)) ions was carried out as a function of pH and initial concentration of Cr(VI) ions. The obtained GO and SBA-16 samples exhibited a superior porosity than that of Cu-MOF, Cu-MOF/GO and Cu-MOF/SBA-16 that owed to close of internal pores in both GO and SBA-16 samples upon loading Cu-MOF particles. The Langmuir and Temkin models prescribed Cr(VI) adsorption more accurately. The maximum adsorption capacity of Cr(VI) was 86.1 mg/g by GO while 77 and 66.7 mg/g by Cu-MOF/GO and Cu-MOF/SBA-16, respectively. The adsorption Cr(VI) mechanism followed the pseudo-first order kinetic model. Therefore, the as-prepared GO and SBA-16 derived from rice husk ash and their composites with Cu-MOF can candidate as effective adsorbents for removal of Cr(IV) ions from their aqueous media.

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